Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 12, Pages 6201-6206Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp4108156
Keywords
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Funding
- MOST [2011CB921404, 2014CB932700]
- NSFC [21173202, 21222304, 21121003]
- CUSF
- CAS [XDB01020300]
- USTC-SCC
- SCCAS
- Tianjin Supercomputer Centers
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From both fundamental and technical points of view, precise control of the layer number of graphene samples is very important. To reach this goal, atomic-scale mechanisms of multilayer graphene growth on metal surfaces should be understood. Although it is a geometrically favorable pathway to transport carbon species to interface and then form a new graphene layer there, penetration of a graphene overlayer is not a chemically straightforward process. In this study, the possibility of different active species penetrating a graphene overlayer on Cu(111) surface is investigated by first-principles calculations. It is found that carbon atom penetration can be realized via an atom-exchange process, which leads to a new graphene growth mechanism. Based on this result, a bilayer graphene growth protocol is proposed to obtain high-quality samples. Such a penetration possibility also provides great flexibility for designed growth of graphene nanostructures.
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