Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 14, Pages 7434-7441Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp500116n
Keywords
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Funding
- National Natural Science Foundation of China [21207145, 51221892]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB05050600]
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Oxygen-deficient TiO2 was prepared with a low-temperature method and utilized in photocatalytic removal of gaseous NO at the 400 ppbv level in air under visible light (420 nm < lambda < 700 nm) irradiation. Catalysts synthesized at 200 degrees C (TiO2-200) exhibited the highest ability to remove the NO gas in air under visible light irradiation. A higher oxidation ability for NO2 to NO3- leads to a higher conversion of NOx on TiO2-200. The relationship between the physicochemical properties and the photocatalytic performance of the as-prepared catalyst is discussed. The large surface area of TiO2-200 can provide more active sites for the reaction. The oxygen vacancies of TiO2-200 can effectively expand the absorption of visible light and accelerate the separation of photogenerated electrons and holes. The first-principles density functional theory (DFT) calculation further confirms the role of oxygen vacancies on the narrowing of the band gap and separating of photogenerated electron-hole pairs.
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