4.6 Article

Soft-Chemical Synthetic Nonstoichiometric Bi2O2.33 Nanoflower: A New Room-Temperature Ferromagnetic Semiconductor

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 46, Pages 27170-27174

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp509045d

Keywords

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Funding

  1. National Natural Science Foundation of China [11079004, 21331005, 11321503]
  2. Chinese Academy of Science [XDB01020300]
  3. Fundamental Research Funds for the Central University [WK2060190032]
  4. Sciences Research Program of University of Anhui Province [KJ2013B227]

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Bi2O2.33 nanoflowers with pure phase were directly prepared via a solvothermal route. The magnetism behavior of the product was investigated, and the data clearly revealed the room-temperature ferromagnetism of the synthetic sample. This nonstoichiometric bismuth oxide should be the diluted magnetic semiconductors (DMSs). XPS measurements showed that the room-temperature ferromagnetism might be derived from the presence of Bi2+ in the structure. The achievement of the nonstoichiometric Bi2O2.33 DMSs might pave the way for a new understanding of the underlying ferromagnetic mechanism in DMSs materials.

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