Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 41, Pages 23553-23558Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp507687h
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Funding
- office of Vehicle Technologies of the U.S. Department of Energy [DE-AC0205CH11231]
- Welch Foundation [F-1254]
- National Natural Science Foundation in China [21273084]
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With an aim to broaden the understanding of the role of Co3+ in the lithium-rich layered oxide cathodes for lithium-ion batteries, the influence of composition and synthesis temperature on the oxygen loss, reversible capacity, and electrochemical behavior of the xLi(2)MnO(3)-(1 x)LiCoO2 series in the first cycle has been systematically investigated. The charge capacity first increases with increasing x value from 0.2 to 0.6 due to the enhanced oxygen loss, but then decreases with further increase in x from 0.6 to 0.8. Although the discharge capacity shows a trend similar to the charge capacity, the maximum value appears at x = 0.40.5, rather than at x = 0.6 because of its larger irreversible capacity loss. Surprisingly, raising the synthesis temperature from 800 to 1000 degrees C alters the electrochemical behavior of the first charge. The materials synthesized at 900 and 1000 degrees C show a three-step reaction process consisting of the oxidation of Co3+, simultaneous oxidation of Co3+ and O-2, and finally the oxidation of O-2 only, while those synthesized at 800 degrees C exhibit a two-step reaction process composed of Co3+ oxidation and O-2 oxidation occurring separately.
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