Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 38, Pages 21866-21872Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp507030g
Keywords
-
Funding
- U.S. National Science Foundation [NSF-CBET-0929207]
Ask authors/readers for more resources
It is generally recognized that H2O adsorption on a porous material would inhibit H-2 adsorption. However, this paper reports that stable H2O-fiinctionalized zeolitic Zn(2-methylimidazole)2 framework (ZIF-8), which was obtained by the simple water treatment of ZIF-8 at ambient temperature, can increase its H-2 adsorption heat from 5.2 to 10.1 kJ/mol. As a result, the reversible H-2 capacity at ambient temperature increased by 77%. This indicates that H2O functionalization provides a novel approach to enhance ambient-temperature hydrogen storage in ZIF-8 and other metal-organic frameworks.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available