Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 43, Pages 24915-24924Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp505449n
Keywords
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Funding
- Foundation for Polish Science - European Union, Regional Development Fund [TEAM/2012-9/4]
- EU-FP7 within the project 4G-PHOTOCAT - Polish Ministry of Science and Higher Education [309636, W13/7.PR/2013]
- European Regional Development Fund [POIG.02.01.00-12-023/08]
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A group of selected hexafluorometallates ([AlF6](3), [TiF6](2), [ZrF6](2), and [SiF6](2)) has been adsorbed at the surface of titanium dioxide. Such modification influenced the electronic and chemical properties of TiO2, as well as its photoactivity. The modification with [TiF6](2) inhibited the efficiency of OH production but enhanced the generation of photocurrent and singlet oxygen. The results of modifications with [ZrF6](2) were the oppositegeneration of 1O(2) was not observed in this case and photocurrents were lower; however, due to a better OH production, degradation of herbicides was faster.
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