Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 119, Issue 1, Pages 45-54Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp508931e
Keywords
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Funding
- University of Wisconsin Materials Research Science and Engineering Center [DMR-1121288]
- National Science Foundation [CBET-1033346]
- DOE Office of Science Early Career Research Program through Office of Basic Energy Sciences [DE- SC0006414]
- U.S. Department of Energy (DOE) [DE-SC0006414] Funding Source: U.S. Department of Energy (DOE)
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Highly transparent and conductive monolayer graphene was used as a template to tune the crystal orientation of pentacene from generic standing-up (001) to lying-down (022) in neat films. Spatially resolved Kelvin probe force microscopy (KPFM) was used to reveal the energy levels of pentacene thin films grown on substrates with and without the template graphene layer, as well as the energy level alignment in various pentacene-containing organicorganic heterojunctions. A correlation between crystal domain orientation and the work function was directly observed using KPFM. Up to 0.36 eV shifts in work function were observed in neat pentacene films over large areas (>0.5 in.(2)) upon orientation transition, likely due to the transition from Fermi level pinning (standing-up pentacene on ITO) to vacuum level alignment (lying-down pentacene on grapheneITO). Morphology-induced energy level shifts versus interfacial electronic equilibration effects were disentangled using atomic force microscopy, KPFM, X-ray diffraction, and Raman data for neat pentacene films and pentacene containing heterojunctions on monolayer graphene. The data detailed herein provide a fundamental picture of the major interfacial effects active in optoelectronic devices containing a bare graphene electrode.
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