4.6 Article

Properties of Chemical Vapor Deposition Graphene Transferred by High-Speed Electrochemical Delamination

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 117, Issue 40, Pages 20833-20837

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp4032139

Keywords

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Funding

  1. European Commission [CNECT-ICT-604391]
  2. National Center for Research and Development [GRAF-TECH/NCBiR/01/32/2012]
  3. [POIG.01.01.02-00-015/09-00]

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We report on the electrical characterization and Raman spectroscopy of chemical vapor deposition copper-grown graphene transferred onto a Si/SiO2 substrate by highspeed (1 mm/s) electrochemical delamination. We determine graphene's sheet resistance, carrier mobility, and concentration as well as its physical quality as a function of the electolyte concentration. Graphene's electrical properties are investigated with standard Hall measurements in van der Pauw geometry and a contactless method that employs a single-post dielectric resonator operating at microwave frequencies. These properties are related to the widely used copper etching technique. The results prove that the high-speed electrochemical delamination provides good-quality graphene within a short time scale.

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