Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 117, Issue 46, Pages 24471-24478Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp409058t
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Funding
- DFG [SFB 762]
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Nanostructure-related magnetic properties are investigated systematically for various mesoporous cobalt oxide (CO3O4) and cobalt ferrite (CoFe2O4) spinel phases. Synthesis of the materials by nanocasting offers the opportunity to obtain materials which are different from each other with respect to both specific surface area and crystallite size. As a result, the respective contributions of two types of interfaces, namely, solid-gas and solid-solid interfaces, to the magnetic ordering can be distinguished. Structural characterization of the porous materials by X-ray diffraction, N-2 physisorption, and electron microscopy as well as investigation of the magnetic behavior (field-dependent magnetization and temperature-dependent susceptibility) are presented.
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