Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 117, Issue 11, Pages 5765-5773Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp312060f
Keywords
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Funding
- EPSRC through an EPSRC-NSF Materials World Network [EP/H047786/1]
- Diamond Light Source Ltd [SP-7405]
- EPSRC [EP/H047786/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H047786/1] Funding Source: researchfish
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A windowless electrochemical cell for the spectroscopic investigation of the liquid-liquid interface, using a dual droplet configuration, has been designed. The setup permits in situ probing of the bulk solutions and the interfacial region by fiber-optic UV-vis spectroscopy, microfocus X-ray fluorescence (XRF) elemental mapping, and microfocus X-ray absorption near-edge structure (mu XANES) spectroscopy. The electrodeposition of Au, induced by ion transfer of the tetrachloroaurate complex from a halogenated solvent (containing a weak reducing agent) to the aqueous phase, has been monitored by a combination of the three techniques. The reaction can be followed in situ by UV-vis spectroscopy by detecting the oxidized form of the reducing agent. Voltammetric evidence suggests the formation of interfacial Au(I) species, whereas mu XANES detect the presence of metallic Au(0).
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