Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 26, Pages 14022-14030Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp303273q
Keywords
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Funding
- CNPq [471220/2010-8]
- FAPERGS [11/2000-4]
- CAPES (Brazilian funding agencies)
- PD ANEEL-CEEE GT [9945481]
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Freestanding tantalum oxide nanotubes (Ta2O5 NTs) were easily fabricated by controlling only the electrolyte temperature during anodization in a sulfuric acid solution. When the electrolyte temperature decreased, the adherence of NTs to the Ta substrate increased. High electrolyte temperatures facilitated formation of freestanding NTs. Thermal treatment of the freestanding Ta2O5 NTs below 750 degrees C resulted in an amorphous structure. The orthorhombic crystalline phase appeared only at temperatures higher than 750 degrees C. The effect of thermal treatment on the crystalline structure and morphology of Ta2O5 NTs showed that the NTs retained their tubular shape up to 800 degrees C. In addition, it was shown that the crystallinity of the NTs was enhanced from 11% to 34% by increasing the treatment time for the NTs at 800 degrees C from 0.5 to 1 h. High crystallinity and low surface contamination increased the photocatalytic activity of the freestanding NTs for hydrogen production by water splitting using a water/ethanol solution under UV radiation. The sample annealed at 800 degrees C for 1 h showed the highest photocatalytic activity for hydrogen generation. Additionally, changes to the physicochemical properties of the surface and bulk of the photocatalyst showed decreased selectivity for minor products (C2H4 and C2H6).
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