Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 27, Pages 14188-14198Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp3009546
Keywords
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Funding
- National Natural Science Foundation of China [51173048, 50990065, 51010003, 51173049]
- Ministry of Science and Technology of China [2009CB623600]
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In this work, poly[N-9'-heptadecany1-2,7-carbazole-alt-5,5-(4,7-di-2-thienyl-5,6-bis(dodecyloxy)-2,1,3-benzothiadiazole)] (PCDTBT12) was synthesized as the polymer donor for photovoltaic application. PCDTBT12 possesses a band gap of 1.99 eV, a low-lying HOMO of -5.6 eV, and good hole mobility up to 4.1 X 10(-3) cm(2) V-1 s(-1) With ZnO as the interlayer on an ITO cathode, a PCDTBT12-based inverted solar cell showed a high open circuit voltage of 0.98 V and a good power conversion efficiency (PCE) of 5.53%, suggesting that PCDTBT12 would be a promising donor material in the fabrication of a subcell for shorter wavelength absorption in a tandem solar cell. Using PC P, a homopolymer of 2,7-carbazole with hydrophilic phosphonate side chains, as an interlayer polymer on the ITO cathode could further elevate the efficiency to 6.04% because of increased current (higher efficiency of 6.2% was achieved for a smaller cell area of 0.045 cm(2)). The efficiencies are the highest ones so far reported for an inverted solar cell with an organic cathode interlayer. It was proposed that the hydrophilic side chains of PC-P supplied a subgap state for electron transport The two devices showed comparable air stability, and retained over 96% of their initial PCEs after storage in air for more than 1 month. Therefore, a hydrophilic conjugated polymer as the cathode interlayer, already shown in outstanding cathode modifications in conventional polymer solar cells, will play an important role in the future development of high efficiency and air stable inverted solar cells.
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