Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 22, Pages 12187-12195Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp212257f
Keywords
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Funding
- 973 project [2009CB930601]
- 863 project [2011AA050526]
- National Natural Science Foundation of China [21003076, 21001065, 61076016, 20974046, 61077070, 61077021]
- Natural Science Foundation of Jiangsu Province [BZ2010043]
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This study developed a new solid-state, highly emissive phenylbenzoxazole-based organic compound, N-(4-(benzo[d]oxazol-2-yl)phenyl)-4-tert-butylbenzamide, which exhibited a distinct aggregation-induced enhanced emission. The solid fluorescence efficiency of the newly developed compound was 50.3%, whereas that in THF solution was only 0.22%. The single-crystal analyses revealed that a specific three-dimensional #-shaped cross stacking between molecules was observed in the solid/aggregated state, driven by specific C-H center dot center dot center dot pi interaction and various hydrogen bonds. The expansion of the cross-dipole stacking into the three-dimensional network was believed to be the dominant factor for the emission enhancement in the solids/aggregates, with respect to the assistant effect of the photoinduced twisted intramolecular charge transfer restriction.
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