Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 16, Pages 9166-9179Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp2109829
Keywords
-
Funding
- Natural Science Foundation of China [20803059, 21173169]
- Chongqing Municipal Natural Science Foundation [2009BB6002]
- National Science Council of the Republic of China [97-2113-M-009-010-MY3]
Ask authors/readers for more resources
A mass of porphyrin sensitizers have been designed and synthesized for dye-sensitized solar cells in previous works, and almost all of them incorporated an electron-rich system as the pi-spacer. We here adopted the electron-deficient pyrimidine as an effective pi-spacer and combined a cyanoacrylic acid anchoring group, as such a design yields a more bathochromic shift of the spectral absorption of the dye and results in an improved spectral overlap with the solar spectrum and an enhanced light-harvesting efficiency. The result does tally with the performance of sensitizer adsorbing on a semiconductor. From the electron density difference plots of electron transitions, we found that not all electron transitions could make for the effective electron transfer from donor to acceptor groups, which means the sensitizer performance in dye-sensitized solar cells not only relies on the extrinsic spectral absorption intensity but also depends on the intrinsic character of electron movement related to electron excitation. Moreover, the introduction of electron-deficient pyrimidine could affect the energy levels of excited molecules in solution, further affecting the kinds of electron transfer processes. We presented several novel porphyrin sensitizers for comparison on how the pi-spacer and anchoring group influence the optical absorption, electron transfer processes, and regeneration of the oxidized dyes, thereby gaining potential dye-sensitized solar cells with highly efficient photo-to-electric conversion performances.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available