Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 7, Pages 4349-4355Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp205088x
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Funding
- Region Ile-de-France
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In this work, we investigate the effect of cobalt substitution on the size evolution, crystal structure, and magnetic properties of Fe3O4 nanoparticles. Monodisperse CoxFe3-xO4 nanoparticles were prepared, using a one-step method, by direct heating process of iron(III) and cobalt(II) acetylacetonates in high-boiling-point inert organic solvent. The quantities of precursors added were based on stoichiometric Fe/Co ratio of desired ferrite. Elemental analyses ICP-AES evidenced successful cobalt doping. The doped particles showed a cobalt-deficient composition. Transmission electron microscopy demonstrated the large changes of particle size as a function of cobalt doping. The magnetization measurements showed an unchanged saturation magnetization only up to x = 0.24, beyond which it significantly decreased. To make the as-synthesized nanoparticles suitable for biomedical applications, oleic acid ligands are exchanged with caffeic acid molecules leading to stable nanoparticles in physiological conditions.
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