Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 14, Pages 7741-7747Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp210386c
Keywords
-
Funding
- NEDO (New Energy and Industrial Technology Development)
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT) [21760023]
- Grants-in-Aid for Scientific Research [21760023] Funding Source: KAKEN
Ask authors/readers for more resources
The adsorption property of CO on Fe clusters deposited on a graphite surface has been studied by temperature-programmed desorption (TPD), scanning tunneling microscopy (STM), and helium atom scattering (HAS). The desorption peak of CO is observed at ca. 330 K (or lower) independent of the amount of the deposited Fe clusters, which is much lower than those reported for single crystal surfaces of Fe. The significant reduction of the adsorption energy of CO has been ascribed to the interface interaction between Fe clusters and the graphite surface. It is also suggested that the carbonylation of Fe clusters (Fe(CO)(x), x = 1-5) takes place by the multiple CO adsorption.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
