Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 49, Pages 25993-25999Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp308969j
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Funding
- MEC Project [CTQ2011-28079-CO3-02]
- ERDF funds
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Prussian blue-modified electrodes immersed in K+-containing solutions can be used to obtain a solvent-independent redox potential system. On the basis of theoretical modeling of diffusion processes occurring under the conditions of voltammetry of immobilized particles, voltammetric and chronoamperometric data can be combined to obtain solvent-independent electrode potentials for the K+-assisted one-electron reduction of Prussian blue to Berlin white. Data for water, MeOH, EtOH, MeCN, DMS, DMF, and NM are provided.
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