Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 116, Issue 49, Pages 25977-25983Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp308966w
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Funding
- MEC Project [CTQ2011-28079-CO3-02]
- ERDF funds
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A formally solvent-independent redox system can be theoretically defined using the Lovric and Scholz modeling of the voltammetry of microparticles for ion-insertion solids. The proposed theory is based on the extra-thermodynamic assumptions that no net charge accumulates at the solidlelectrolyte interface and the assumption that the structure of the solid and the ion binding remain unaffected by the solvent. Under voltammetric conditions, the corresponding redox potential can be estimated from voltammetric and chronoamperometric data assuming electrochemical reversibility and diffusive charge transport in the solution and solid phases, also taking into account ion partition (electrolyte/solid) and ion-binding equilibria.
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