Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 14, Pages 6381-6391Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp2003968
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Funding
- Universita' degli Studi di Milano
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Optical and electrochemical characterizations are carried out in conjunction with first-principles calculations on pure and N-doped titania nanocrystals. These are prepared in laboratory with initial doping concentrations of triethylamine in the range of 0.1-0.5 N/Ti molar ratio. Diffuse reflectance UV-vis spectra of N-doped samples present a significant absorption in the visible region. The flatband potential (E-fb) of pure and nitrogen-doped TiO2 (-0.6 +/- 0.2 V vs NHE) is determined by impedance spectroscopy (Mott-Schottky plots) and the quasi-Fermi level, E-n(F)* (-0.6 (7) over barV vs NHE) by photovoltage measurements as a function of the suspension pH in the presence of an electrochemical probe (methylviologen, MV2+). Theoretical density of electronic states calculations, where several N doping versus vacancy combinations are taken into consideration, together with the optical and electrochemical experiments allow us to draw a detailed picture of the electronic features of the doped samples.
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