Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 29, Pages 14300-14308Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp2042069
Keywords
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Funding
- National Basic Research Program of China (973 Program) [2007CB613301]
- National Science Foundation of China [21073069, 91023010]
- Program for Innovation Team of Hubei Province [2009CDA048]
- CCNU, Colleges' Basic Research and Operation of MOE [CCNU09C01009]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0953]
- Open Fund of Key Laboratory of Catalysis and Materials Science of Hubei Province [CHCL09001]
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In this study, we investigate the photocatalysis mechanism of BiOI in detail and therefore demonstrate that the photocatalytic activity of BiOI could be enhanced greatly by in situ modification of an ionic liquid [Bmim]I (1-buty-3-methylimidazolium iodide). The ionic liquid modified BiOI (IL-BiOI) was prepared by reacting bismuth nitrate with [Bmim]I in water at 70 degrees C, where the ionic liquid could act as both iodine source and surface modified agent. On degradation of methyl orange (MO) under visible light irradiation (lambda > 420 nm), IL-BiOI photocatalyst exhibited superior photocatalytic activity to the unmodified counterpart synthesized in the absence of [Bmim)I. The effects of ionic liquid modification on the photocatalytic activity enhancement were systematically investigated. We found that IL modification could trap the photoexcited electron at conduction band of BiOI to inhibit the recombination of photoinduced electron-hole pairs and thus enhance its photocatalytic activity on the degradation of organic pollutants.
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