Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 18, Pages 9074-9080Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp111978m
Keywords
-
Funding
- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [LAB04-20]
Ask authors/readers for more resources
The structural evolution during dissolution of Cu from Cu3Pt (111) single crystal surfaces under potential control has been studied by X-ray scattering. An epitaxial, compressively strained, Pt-rich overlayer is formed upon Cu dissolution and thickens as the potential increases (more anodic). The compressive lattice strain in the Pt-rich overlayers decreases as the potential and overlayer thickness increase. The Pt-rich overlayers exhibit same fcc stacking sequence as the substrate. We compare and contrast the behavior of the dealloyed single crystals with similarly dealloyed Cu3Pt thin films and nanoparticles.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available