Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 25, Pages 12358-12366Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp203261s
Keywords
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Funding
- National Science Council, Taiwan, Republic of China [NSC 98-2221-E-110-005-MY2]
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In this study, fluorescent organic compound FN and polymer PFN with alternative fluorene and naphthol units were prepared to assess the influence of the hydrogen bonds (H-bonds) on the emission behavior. Both FN and PFN exhibit the enhanced aggregation emission behavior with enhanced emissions on solution mixtures of higher degree of aggregation. For solid FN and PFN films, the fractions of the H-bonded hydroxyl groups decrease upon being heated to high temperature, which results in aggregate dissociation and reductions in the aggregation emissions. Meanwhile, procedures leading to the increase of the H-bonds (such as shearing or enhanced aggregation by addition of nonsolvent in the solution preparative step) resulted in solid films with higher emission intensity. Variations on the H-bonds can be detected by infrared spectroscopy and are in line with the emission behavior.
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