Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 16, Pages 8288-8294Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp1111668
Keywords
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Funding
- Chinese Natural Science Foundation [NSFC 20876101, 21076134]
- NSF of Jiangsu Province [08KJA430004, BK2008158, BK2010208]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20070285003]
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In this paper, one methacrylate monomer contaming naphthalimide as electron acceptor and aromatic hydrazone as electron donor was designed and synthesized. Its copolymer with styrene has been incorporated into sandwiched memory devices which show dynamic random access memory, characteristics with highest ON/OFF current ratio up to 10(6) and a long retention time. Moreover, it was observed that switch threshold voltage of the device varied almost linearly with functional moiety content in the copolymer. The photoluminescence spectra and X-ray diffraction of the copolymer's film were investigated and the results showed that the functional moieties in the pendant chains occurred as pi-pi stacking and the distance between each other became closer as the functional moieties content in the copolymer increased The mechanisms associated with dram characteristics were elucidated from molecular simulation results that the slight electron density transition from the HOMO to LUMO surfaces would easily revert to original state once the external electric field was removed.
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