Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 13, Pages 5373-5377Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp110527c
Keywords
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Funding
- Air Force Office of Scientific Research [FA9550-10-1-0071]
- U.S. Department of the Army through a MURI [W911NF-06-1-0280]
- Kavli Foundation
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Small aluminum clusters (< 30 atoms) have been the subject of extensive study, demonstrating markedly different properties as even a single atom is added or removed. Successfully depositing and characterizing mass-selected clusters are the next steps in producing precise surfaces or cluster-assembled materials that demonstrate properties that differ from those of bulk materials. This proves to be difficult due to the reactivity of these all-metal clusters and their susceptibility to agglomerate in bulk form. In the present study, we have successfully deposited Al-17(-) onto self-assembled monolayers using reactivity previously characterized in the gas phase.
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