Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 39, Pages 19041-19048Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp206167j
Keywords
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Funding
- Israel Science Foundation (ISF) [447/09]
- ERC [246754]
- Perlman Family Foundation
- U.S. National Science Foundation [OISE-0965137]
- United States-Israel Educational Foundation/Fulbright commission in Israel
- Helen and Kimmel Award for Innovative Investigation
- Office Of The Director
- Office Of Internatl Science &Engineering [0965137] Funding Source: National Science Foundation
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This work examines several polycrystalline diamond samples for their potential as polarizing agents for dynamic nuclear polarization (DNP) in NMR. Diamond samples of various origin and particle sizes ranging from a few nanometers to micrometers were examined by EPR, solid-state NMR and DNP techniques. A correlation was found between the size of the diamond particles and the electron spin-lattice relaxation time, the C-13 nuclear spin-lattice relaxation times in room temperature magic-angle-spinning experiments, and the ability of the diamond carbons to be hyperpolarized by irradiating unpaired electrons of inherent defects by microwaves at cryogenic temperatures. As the size of the diamond particles approaches that of bulk diamond, both electron and nuclear relaxation times become longer. NMR signal enhancement through diamond samples. The reasons and implications of these results are observations. DNP was found to be very efficient only for these larger size briefly discussed, in the light of these EPR, DNP, and NMR
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