Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 11, Pages 4721-4725Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp1112944
Keywords
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Funding
- Shanghai Education Committee, the National Science Foundation of China
- Research Grant Council of Hong Kong [402309]
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On the basis of a carbon nanotube intramolecular junction and a C-60, a molecular sieve for H-2 is proposed. The small interspace formed between C-60 and the junction provides a size changeable nanochannel for the permselectivity of H-2 while blocking Ne and Ar. The sieving mechanism is discussed in terms of soft repulsion of H-2 and the size of the nanochannel.
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