Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 115, Issue 28, Pages 13577-13583Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp201795y
Keywords
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Funding
- MICINN (Spain) [MAT 2010-21088-C03-01]
- MICINN ACT PLAN E (JAPON) [PLE2009-0073]
- European Comission [ERC-2008-Stg: 240497]
- JAE
- Conseil Regional du Limousin
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The formation of Ni1-xZnxO rock salt solid solution is obtained by thermal treatments applied to NiO nanoparticles supported on ZnO micrometric particles. The high vapor pressure of ZnO produces a Zn-rich atmosphere during thermal treatment. The Zn ions tend to be adsorbed by the highly reactive NiO nanoparticles. When heated to temperatures high enough, over 500 degrees C, the Zn ions react with the NiO nanoparticles forming the rock salt material. By variation of the treatment temperature, the composition of this rock salt structure can be varied through the whole solubility range.
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