Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 6, Pages 2600-2603Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp907682x
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Funding
- Global COE for Materials Research and Education
- WPI Initiative for Atoms, Molecules and Materials
- MEXT, Japan
- Iketani Science and Technology Foundation
- Murata Science Foundation
- Inamori Foundation
- JSPS Postdoctoral Fellowship [P07373]
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A novel nanoporous gold-palladium alloy has been successfully fabricated by electrochemically dealloying a multicomponent metallic glass. In comparison with conventional nanoporous gold prepared by dealloying Au-Ag alloys, the nanoporous gold-palladium alloy shows much higher catalytic activity for electrooxidation of methanol as a free-standing electrode. Moreover, a small amount of palladium in the nanoporous alloy is found to dramatically improve the electrochemical stability of nanoporous gold.
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