4.6 Article

Graphene Films and Ribbons for Sensing of O2, and 100 ppm of CO and NO2 in Practical Conditions

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 14, Pages 6610-6613

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp100343d

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Funding

  1. National Science Foundation through NIRT [ECS 0404137]

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Graphene films and ribbons were grown on Ni-coated Si substrates using the microwave plasma enhanced chemical vapor deposition method. We report the structure, morphology, and quality of graphene films and ribbons. The semiconducting nature of the CVD-grown graphene was observed by studying resistance temperature variation in the ranee 25 to 200 degrees C, using the lour-point probe method Graphene exhibited an increase of resistance upon exposure of CO and a decrease in resistance upon pure O-2 and NO2 exposures It was observed that graphene films show sensor signal similar to 3 and 35 for 100 ppm of CO and 100 ppm of NO2 whereas the graphene ribbons show the sensor signal values of 15 and 18 for 100 ppm of CO and 100 ppm of NO2. The gas sensor mechanism was observed to be mainly dependent on the charge carrier transfer on conducting graphene surfaces caused by the adsorption of gases.

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