4.6 Article

Fabrication of CdSe Nanoparticles Sensitized Long TiO2 Nanotube Arrays for Photocatalytic Degradation of Anthracene-9-carbonxylic Acid under Green Monochromatic Light

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 11, Pages 4783-4789

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp910489h

Keywords

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Funding

  1. National Science Foundation for Distinguished Young Scholars [50725825]
  2. National Science Foundation of China [50878079]
  3. National Basic Research Program of China [2009CB421601]
  4. Natural Science Foundation of Hunan Province, China [08JJ3113]

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CdSe nanoparticles with well dispersion were decorated oil inner and outer surfaces of 4 mu m long TiO2 nanotubes through a simple direct current electrotechnique, resulting in a composite functional material with a perfect construction. The applied depositing voltage plays a determinative role during the CdSe nanoparticles formation process, getting through the breakdown potential of TiO2 and providing intense active sites for the CdSe crystal growth oil the TiO2, nanotubes. The CdSe/TiO2, composite nanotube arrays exhibit high absorption in the visible light region due to the narrow band gap of CdSe, and depict sensitive photoelectrochemical response Under visible light illumination. Photocatalytic degradation of anthracene-9-carbonxylic acid (ACA), one of the derivants of persistent organic pollutants (POPS), was successfully achieved oil CdSe/TiO2, nanotubes when exposed to the 550 nm green monochromatic light.

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