Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 32, Pages 13608-13613Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp105146c
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Funding
- Ministry of Education [MOE2008-T2-1-004]
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Nanotubular ruthenium oxides were prepared by using manganite nanorods as a morphology sacrificial template. Experimental results showed that the template dissolved away completely during the formation of the ruthenium oxide nanotubes. A mechanism was proposed to interpret the formation of the ruthenium oxide nanotubes. The electrochemical capacitive properties of the ruthenium oxide nanotubes were investigated using cyclic voltammetry and charge/discharge techniques with H2SO4 and Na2SO4 solutions as the electrolytes, respectively. The specific capacitance of the nanotubular ruthenium oxide electrode was measured to be as high as 860 F/g at a current density of 500 mA/g in the H2SO4 electrolyte, which was higher than that obtained in the Na2SO4 electrolyte. In addition, the ruthenium oxide nanotubes were observed to exhibit a good capacitive retention at high current loads.
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