4.6 Article

Mode-Switching of the Self-Motion of a Camphor Boat Depending on the Diffusion Distance of Camphor Molecules

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 21, Pages 9876-9882

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp101838h

Keywords

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Funding

  1. Asahi Glass Foundation
  2. Grant-in-Aid for the Global COE Program Formation and Development of Mathematical Sciences Based on Modeling and Analysis
  3. [21340023]
  4. [20550124]
  5. [21740282]
  6. Grants-in-Aid for Scientific Research [21740282, 21340023] Funding Source: KAKEN

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We demonstrated mode-switching of self-motion coupled with diffusion of molecules at a solid/liquid interface. A camphor boat moved spontaneously on water and the mode of self-motion depended on the setup of the boat. When a camphor disk was connected to the center of a larger plastic plate, intermittent motion (alternating between rest and rapid motion) was observed. When the position of the camphor disk was changed from the center to one of its edges, the period of intermittent motion decreased, and intermittent motion changed to continuous motion. The features of this self-motion and mode-switching were qualitatively reproduced by a numerical calculation using a mathematical model that incorporates the distribution of camphor molecules at the solid/liquid interface.

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