Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 14, Pages 6503-6510Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp911839b
Keywords
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Funding
- Spanish MICINN [NAN2004-08881-C02-01, FIS2007-61114, FIS2007-66711-C02-01, FIS2007-60064, MAT2007-66719-C03-03, CT2008-00795/BQU]
- Comunidad de Madrid [GR/MAT/0435/2004, P-PPQ-000225-0505, S-0505/MAT/0194]
- GV-UPV/EHU [IT-366-07]
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The adsorption of a TTF derivative (2-[9-(1,3-dithrol-2-ylidene)anthracen-10(9H)-ylidene-]-1,3-dithiole, exTTF) on Au(111) has been studied by a combination of scanning tunneling microscopy. photoelectron spectroscopy, and theoretical calculations The results indicate that the molecule-substrate interaction is dominated by the S Au bonds However. due to conformational reasons, only one of the two dithiole rings is in close contact with the surface. As a consequence. the interaction with the Au surface is much smaller (less than half) the interaction of TTF with Au(111), where the four sulfur atoms are in direct contact
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