Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 114, Issue 1, Pages 601-609Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp908886d
Keywords
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Funding
- National Natural Science Foundation of China [50773057, 90922020, 20621401]
- National Basic Research Program of China [2009CB623602, 2009CB930603]
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A series of new 1,2,4-triazole-cored triphenylamine derivatives with various linkages between triazole and triphenylamine (TPA) moieties were designed and synthesized through Suzuki cross-coupling reaction. The incorporation of rigid triazole moiety greatly improves their thermal and morphology stability, with T-d and T, in the ranges 480-531 degrees C and 106-155 degrees C, respectively. The o-TPA-linked 7 and 8 show much less intramolecular charge transfer and blue-shifted emission than their p-TPA linked analogues I and 3, respectively. The meta- and ortho-structured compounds display higher triplet energy and better electrophophorescent performances than their para-structured congeners. The significant improvement of electrophosphorescent performances can be achieved through subtle change of the host molecular structures, which could be attributed to the well-matched energy levels between the host and hole-transport layer, the high triplet energy of the host, and complete spatial separation of HOMO and LUMO energy levels. Devices hosted by structure-optimized o-TPA-m-PTAZ achieve the best EL performance, with the maximum current efficiencies and maximum external quantum efficiencies as high as 12.4 cd/A and 16.4% for deep red electrophosphorescence, and 50.7 cd/A and 14.2% for green electrophosphorescence.
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