L-Lysine-Assisted Synthesis of ZrO2 Nanocrystals and Their Application in Photocatalysis

Nanocrystalline ZrO2 with narrow size distribution and mean size similar to 8 nm has been synthesized by the 1-lysine-assisted hydrothermal method. The structural and morphological characterizations were studied by powder. X-ray diffraction (XRD) and transmission electron microscopy (TEM), and physicochemical characterizations were carried out by using infrared spectra (IR), UV-vis spectra, and photoluminescence (PL) spectra. On the basis of the choice of synthesis parameters., monoclinic (m-) and tetragonal (t-) phases of ZrO2 coexisted with a size similar to 8 nm. This is an important result with respect to application in catalytic properties of nanocryalline ZrO2. The possible nucleation and growth process is also discussed.