4.6 Article

Nanoparticle-Enhanced Photopolymerization

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 113, Issue 27, Pages 11720-11724

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp901773k

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan [470 (19049001), 20710068]
  2. Hokkaido Innovation through Nanotechnology Support (HINTS).
  3. Grants-in-Aid for Scientific Research [20710068] Funding Source: KAKEN

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Photopolymerization of commercial photoresist SU-8 assisted by plasmonic near-field enhancement in nanogaps separating gold nanoblocks was investigated. Photopolymerization rates enhanced by orders of magnitude were found in gold nanoblock structures with nanogaps narrower than 10 nm. The mechanisms responsible for local and nonlocal nonlinear photopolymerization of SU-8 are discussed.

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