Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 113, Issue 25, Pages 11003-11013Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp902688b
Keywords
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Funding
- Major State Basic Resource Development Program [2003CB615807]
- NSFC [20573024]
- Natural Science Foundation of Shanghai Science & Technology Committee [06JC14004]
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Copper-containing mesoporous HMS catalysts prepared via a one-pot synthesis method based on sol-gel chemistry have been systematically characterized focusing on the effect of copper loading. Structural characterization of a series of different copper loading samples was performed by means of N-2 adsorption, X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, temperature programmed reduction, N2O titration, and X-ray photoelectron spectroscopy. It is concluded that the copper loading has a great influence on the pore structure of the catalyst. On the basis of the characterizations, the copper species on calcined CuO/HMS samples and reduced Cu/HMS samples were assigned. The synergetic effect between the Cu-0 and Cu+ is considered to be responsible for the enhanced catalytic performance in the hydrogenation of dimethyl oxalate (DMO) to ethylene glycol (EG). The maximum ratio of Cu-0/Cu+ obtained via tuning the copper loading can result in the highest DMO hydrogenation activity and EG selectivity.
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