Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 41, Pages 16036-16041Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp802955s
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Funding
- Program for Strategic Scientific Alliances between China and The Netherlands (PSA)
- Royal Netherlands Academy of Arts and Sciences (KNAW) [04-PSA-M-01]
- National Basic Research Program of China [2004CB720607]
- NSFC [20621063]
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The transition metal containing zeolites show high selectivity and activity in many catalytic reactions under mild conditions; however, detailed characterization of transition metal site ions and the nature of the active sites remain elusive. Here, we present a study of the framework Fe ions in Fe-ZSM-5 zeolite via interplay between resonance Raman spectroscopy excited by 244 and 532 nm laser lines and density functional theory (DFT) calculations. Raman bands at 1165, 1115, 1005, and 516 cm(-1) from the framework iron ions in the framework of Fe-ZSM-5 were observed. On the basis of the DFT calculations, the bands at 1165, 1115, and 516 cm(-1) were attributed to v(0)(A(1)), v(1)(A(1)), and v(2)(A(1)) modes with totally symmetric vibration of FeO4 tetrahedron in Fe-ZSM-5, originating from resonant enhanced Raman scattering, while the band at 1005 cm(-1) for V-6(T-2) was identified as a nontotally symmetric vibration of the FeO4 tetrahedron from normal Raman scattering. The present work indicates that the resonance Raman bands at 500 and 1100 cm(-1) can be used as the spectral characteristics of the transition metal ions substituted in the framework of zeolites.
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