4.6 Article

White up-conversion luminescence in rare-earth-lon-doped YAlO3 nanocrystals

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 38, Pages 15071-15074

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp805205v

Keywords

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Funding

  1. National Defense Science Innovative Foundation Project of Chinese Academy of Sciences [CXJJ-182]
  2. Science & Technology Plan Project of Fujian Province of China [2005HZ1026, 2007H0037]
  3. FJIRSM [SZD08001-2]

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Room-temperature bright white up-conversion (UC) luminescence in Yb3+/Er3+/Tm3+ ion-doped YAlO3 nanocrystals was achieved under diode laser excitation of 974.5 nm. The white light consists of the blue ((1)G(4) -> H-3(6) of Tm3+), green (H-2(11/2)/ S-4(3/2) -> I-4(15/2) of Er3+), and red ((1)G(4) -> F-3(4) of Tm3+ and I-4(15/2) -> I-4(15/2) of Er3+) UC emissions. The UC mechanisms were proposed based on spectral, pump power dependence and kinetic analyses. The white light may be a possible candidate for applications in the field of lighting, displays, and photonics.

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