Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 5, Pages 1463-1467Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp077729f
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The growth of ZnS nanoparticles during precipitation from aqueous solution is studied by in situ stopped-flow UV absorption spectroscopy at temperatures between 283 and 323 K. Particle growth is marked by substantial ripening during the first 60 ms. Kinetic data suggest that a ripening mechanism by coalescence. (oriented attachment) is predominant over Ostwald ripening, although the latter seems to coexist to a significant degree at early temporal stages, predominantly at low temperatures.
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