Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 39, Pages 15236-15240Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp804235a
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Funding
- Deutsche Forschungsgemeinschaft [SFB 569]
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An oligopyridine forms a well-ordered two-dimensional network at the graphite-liquid interface stabilized by weak hydrogen bonds. This network offers two types of geometrically different voids of similar size, oval and circular in shape, respectively. Hierarchical coadsorption of C-60 fullerene onto the oligopyridine monolayer leads to a host-guest network in which the fullerene molecules adsorb exclusively in the circularly shaped voids. This is attributed to the fit of the spherical molecules to the round void according to a geometric lock-and-key principle.
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