4.6 Article

Birnessite-type MnO2 Nanowalls and Their Magnetic Properties

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 44, Pages 17089-17094

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp804673n

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Funding

  1. National Basic Research Program of China [2007CB925003]
  2. Chinese Academy of Sciences

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Birnessite-type MnO2 nanowalls have been fabricated on Si(111) substrate by a facile solution method. The XRD pattern indicates that the sample has the typical feature of turbostratic disorder and prefers to grow in the ab plane. The nanowalls are composed of thin flakes distributing uniformly over the surface of the Si(111) substrate. A magnetic transition temperature of 9.2 K is determined. Prominent magnetic anisotropy with the easy magnetization direction in the ab plane is observed at 5 K.

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