4.6 Article

Surface Enhanced Raman Scattering and Resonance Elastic Scattering from Capped Single Ag Nanoparticles

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 112, Issue 50, Pages 19866-19871

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp804313e

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Funding

  1. U.S. Department of Energy [DE-FG02-06ER46342]
  2. U.S. Department of Energy (DOE) [DE-FG02-06ER46342] Funding Source: U.S. Department of Energy (DOE)

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Capped Ag nanoparticles with the novel silver core-molecule-silver cap structure were synthesized and demonstrated to produce strong SERS. Plasmon-induced electronic coupling was concluded to be the major Raman enhancement mechanism. The capped nanoparticles also exhibited polarization-dependent elastic light scattering that was attributed to the particle anisotropy, which resulted from the addition of the silver cap. These particles can potentially be used as optical labels.

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