Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 118, Issue 31, Pages 9507-9514Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp506013c
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Funding
- National Natural Science Foundation of China [21274154, 51373191]
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Understanding the interactions between solvent molecules and cellulose at a molecular level is still not fully achieved in cellulose/N,N-dimethylacetamide (DMAc)/LiCl system. In this paper, cellobiose was used as the model compound of cellulose to investigate the interactions in cellulose/DMAc/LiCl solution by using Fourier transform infrared spectroscopy (FTIR), C-13, Cl-35, and Li-7 nuclear magnetic resonance (NMR) spectroscopy and conductivity measurements. It was found that when cellulose is dissolved in DMAc/LiCl cosolvent system, the hydroxyl protons of cellulose form strong hydrogen bonds with the Cl-, during which the intermolecular hydrogen bonding networks of cellulose is broken with simultaneous splitting of the Li+-Cl- ion pairs. Simultaneously, the Li+ cations are further solvated by free DMAc molecules, which accompany the hydrogen-bonded Cl- to meet electric balance. Thereafter, the cellulose chains are dispersed in molecular level in the solvent system to form homogeneous solution. This work clarifies the interactions in the cellulose/DMAc/LiCl solution at molecular level and the dissolution mechanism of cellulose in DMAc/LiCl, which is important for understanding the principle for selecting and designing new cellulose solvent systems.
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