4.7 Article

Elastic continuum theory: Towards understanding of the twist-bend nematic phases

Journal

PHYSICAL REVIEW E
Volume 92, Issue 3, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.92.030501

Keywords

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Funding

  1. THALES Program of the Operational Project Education and Lifelong Learning [380170]
  2. European Social Fund
  3. State of Greece
  4. INCT-FCx-National Institute of Science and Technology of Complex Fluids-CNPq/FAPESP (Brazil)

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The twist-bend nematic phase, N-TB, may be viewed as a heliconical molecular arrangement in which the director n precesses uniformly about an extra director field, t. It corresponds to a nematic ground state exhibiting nanoscale periodic modulation. To demonstrate the stability of this phase from the elastic point of view, a natural extension of the Frank elastic energy density is proposed. The elastic energy density is built in terms of the elements of symmetry of the new phase in which intervene the components of these director fields together with the usual Cartesian tensors. It is shown that the ground state corresponds to a deformed state for which K-22 > K-33. In the framework of the model, the phase transition between the usual and the twist-bend nematic phase is of second order with a finite wave vector. The model does not require a negative K-33 in agreement with recent experimental data that yield K-33 > 0. A threshold is predicted for the molecular twist power below which no transition to a twist-bend nematic may occur.

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