Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 117, Issue 38, Pages 11309-11317Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp402413d
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Funding
- Australian Research Council Future Fellowship
- Australian Research Council
- China Scholarship Council
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The absorption and fluorescence spectra of chlorophyll f (newly discovered in 2010) have been measured in acetone and methanol at different temperatures. The spectral analysis and assignment are compared with the spectra of chlorophyll a and d under the same experimental conditions. The spectroscopic properties of these chlorophylls have further been studied by the aid of density functional CAM-B3LYP and high-level symmetric adapted coupled-cluster configuration interaction calculations. The main Q and Soret bands and possible sidebands of chlorophylls have been determined. The photophysical properties of chlorophyll f are discussed.
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