Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 116, Issue 3, Pages 987-991Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp2102989
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Funding
- Procter & Gamble Research
- [TG-MCA93S020]
- [CHE 09-46358]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0946358] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [1120901] Funding Source: National Science Foundation
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A hydrophobic theory is combined with a Debye-Huckel approximation to calculate surfactant micellization properties such as the critical micelle concentration (cmc) and concentration effects. The predictive power of the theory is validated by comparison with experimental data of various ionic surfactant types in presence of salt. The theory is also used to describe micellar properties of surfactant models developed for molecular simulations for which cmc computations become infeasible. The theory allows such computations and helps to evaluate the quality of models used in simulations.
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