Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 114, Issue 34, Pages 11149-11154Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp105317e
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The electrical double-layer structure and capacitance in room temperature ionic liquids at electrified interfaces were systematically studied with use of the self-consistent mean-field theory The capacitance curve departs from symmetry with respect to the point of zero charge when unequal ion-size is implemented or when specific adsorption of ions is introduced For the case of unequal ion-size, the shape of the capacitance curve is strongly determined by the size of the counterion and only weakly influenced by the co-ion size. When present, specifically adsorbed ions would change the capacitance within a limited range of applied potential from the point of zero charge, which itself vanes with the strength of specific adsorption
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