Journal
JOURNAL OF PHYSICAL CHEMISTRY B
Volume 114, Issue 41, Pages 13121-13127Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp104514t
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Funding
- National Natural Science Foundation of China [20974106, 20636050]
- National Natural Science Funds
- NSFC-KOSEF [F01-2009-000-10171-0, 20911140273]
- National Basic Research Program of China [2009CB623403]
- Specialized Research Fund for the Doctoral Program of Higher Education [200803580015]
- China Postdoctoral Science Foundation [20090460060]
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For development of proton conductive membranes, it is a difficult dilemma to balance proton conductivity and methanol permeability; however, this research proposes a simple strategy to solve this problem, i.e., embedding a proton Conductive barrier into the perflorosulfonated matrix. The strategy is exemplified by embedding the amphoteric sulfonated poly(phthalazinone ether sulfone kentone) (SPPESK) into a semicrystalline perflorosulfonic acid polymer matrix (FSP). After being annealed, the domain of SPPESK is converted to the barrier. Two acid-base interactions constitute the barrier for both the transfer of protons and the blockage of methanol, respectively. On one hand, poorly hydrophilic ionic acid-base interactions (-SO3-...NH+-) are formed between sulfonic acid group and phthalazinone group through annealing and are use for methanol blocking. On the other hand, more hydrophilic hydrogen-bonded acid-base interaction (-SO3H...(H2O)(n)...N-, n <= 3) can also be formed under hydrated condition and facilitate proton transport according to the Grotthuss-type mechanism. As a result, the final membrane exhibits an extremely low methanol permeability (30% of that of Nafion-112) and an excellent fuel cell performance (as compared with Nafion-112 at 80 degrees C).
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