4.5 Article

Fine-Tuning the Morphology of Self-Assembled Nanostructures of Propargyl Ammonium-Based Amphiphiles

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 114, Issue 39, Pages 12495-12500

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp104911e

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N-Methyl-N-(pentacosa-10,12-diyn)-propargylamine organizes itself into an unusual supramolecular pH- and thermo-responsive system. Studies have showed that submillimetric length hollow laths form this unique structure in the presence of hydrochloric acid. Specific chemical modifications on the initial molecule and small-angle neutron scattering experiments were performed to understand the structure of this system. Our results allow us to suggest a possible structure of the laths.

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